Warm and Slightly Reduced Mantle Under the Off-Rift Snæfellsnes Volcanic Zone, Iceland
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Warm and Slightly Reduced Mantle Under the Off-Rift Snæfellsnes Volcanic Zone, Iceland. / van der Meer, Quinten H. A.; Bali, Enikö; Guðfinnsson, Guðmundur H.; Kahl, Maren; Rasmussen, Maja B.
In: Journal of Petrology, Vol. 62, No. 12, egab057, 2021.Research output: Contribution to journal › Journal article › Research › peer-review
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TY - JOUR
T1 - Warm and Slightly Reduced Mantle Under the Off-Rift Snæfellsnes Volcanic Zone, Iceland
AU - van der Meer, Quinten H. A.
AU - Bali, Enikö
AU - Guðfinnsson, Guðmundur H.
AU - Kahl, Maren
AU - Rasmussen, Maja B.
N1 - Publisher Copyright: © 2021 Oxford University Press. All rights reserved.
PY - 2021
Y1 - 2021
N2 - Olivine (Fo75-91) with spinel inclusions (Cr# 10 61) in basaltic lavas/tephras from the off-rift Snefellsnes Volcanic Zone in Iceland record the chemistry, temperature and oxygen fugacity of fractionating magmas. After a detailed assessment of equilibrium conditions, crystallization temperatures and oxygen fugacity can be calculated from the composition of homogeneous Cr-spinel and Al-chromite inclusions in olivine phenocrysts. Geologically meaningful results can occasionally be obtained when homogenous spinel is enclosed in mildly zoned olivine and KD Mg-Fe [(Mg/ Fe)olivine/(Mg/Fe2 )spinel] is within the range for homogenous spinel in homogeneous olivine (3.5 4.3 for our samples). Spinel in normal zoned Fo84.7 90.9 olivine records the primitive stages of magma fractionation and has crystallized from clinopyroxene-free primitive melts, probably at Moho depth and/or below. Discrepancies between Tol-liq (Mg-Fe2 diffusion sensitive) and TAL (diffusion insensitive) suggest that some primitive olivines experienced magma mixing, completely overprinting their Fo content. Consequentially, Tol-liq in primitive olivines occasionally records residence rather than crystallization conditions. Temperature (1187 1317C) gradually decreases across normal zoned Fo84.7 90.9 olivine and controls fO2 (Dlog fO2 (QFM) 0.660.2). Rechargerelated primitive Fo83.8 86.8 mantles of reverse zoned olivine contain the most primitive Cr-spinel linked to crustal magma storage zones. These spinels are mostly antecrysts with high Cr# (41.1 47.9) similar to spinel in normal zoned olivines that were captured by olivine and equilibrated in terms of Mg-Fe2 . A rare olivine macrocryst crystallized alongside clinopyroxene (wehrlite) and includes abundant homogeneous Al-rich Cr-spinels. These are unique because they appear to record closed-system fractional crystallization rather than magma mixing and because they show that Cr-poor, Al-rich spinel crystallized alongside clinopyroxene. The macrocryst olivine spinel pairs record lower crustal crystal mush conditions with fO2 around the QFM buffer and Tol-liq of 1200C, similar to recharge-related mantles of reverse zoned olivine. More evolved compositions occur in the cores of reverse zoned olivine (Fo75-85) that contain Cr-spinel, Fe-spinel and Almagnetite. Contrary to spinel in more primitive olivine, these compositions are diverse and follow increasing 100Fe3 /(Cr Al Fe3 ) of 12.3 to 54.8 and TiO2 (3.3 to 14.7 wt %) at decreasing Mg# (57.4 to 24.1) and Cr# (30.4 to 9.9) and rapidly increasing oxygen fugacities (Dlog fO2 (QFM) 0.2 to 2.0) over only a limited temperature decrease (Tol-liq: 1190 to 1145C). These compositions span the spinel gap and are extremely rare globally. Their preservation is probably related to hightemperature crystallization followed by rapid cooling. These compositions occur at two of the four investigated volcanic centres (Buoahraun and Berserkjahraun) and indicate a strong influence of crustal magmatic processes on crystal composition and fO2, which is absent in the other two locations (Olafsvikurenni and Nykurhraun). Spinel and olivine compositions support the tectonically controlled decompression melting of a fertile peridotitic source at elevated mantle temperatures relative to MORB and more reducing conditions than other off-rift magmatism in Iceland.
AB - Olivine (Fo75-91) with spinel inclusions (Cr# 10 61) in basaltic lavas/tephras from the off-rift Snefellsnes Volcanic Zone in Iceland record the chemistry, temperature and oxygen fugacity of fractionating magmas. After a detailed assessment of equilibrium conditions, crystallization temperatures and oxygen fugacity can be calculated from the composition of homogeneous Cr-spinel and Al-chromite inclusions in olivine phenocrysts. Geologically meaningful results can occasionally be obtained when homogenous spinel is enclosed in mildly zoned olivine and KD Mg-Fe [(Mg/ Fe)olivine/(Mg/Fe2 )spinel] is within the range for homogenous spinel in homogeneous olivine (3.5 4.3 for our samples). Spinel in normal zoned Fo84.7 90.9 olivine records the primitive stages of magma fractionation and has crystallized from clinopyroxene-free primitive melts, probably at Moho depth and/or below. Discrepancies between Tol-liq (Mg-Fe2 diffusion sensitive) and TAL (diffusion insensitive) suggest that some primitive olivines experienced magma mixing, completely overprinting their Fo content. Consequentially, Tol-liq in primitive olivines occasionally records residence rather than crystallization conditions. Temperature (1187 1317C) gradually decreases across normal zoned Fo84.7 90.9 olivine and controls fO2 (Dlog fO2 (QFM) 0.660.2). Rechargerelated primitive Fo83.8 86.8 mantles of reverse zoned olivine contain the most primitive Cr-spinel linked to crustal magma storage zones. These spinels are mostly antecrysts with high Cr# (41.1 47.9) similar to spinel in normal zoned olivines that were captured by olivine and equilibrated in terms of Mg-Fe2 . A rare olivine macrocryst crystallized alongside clinopyroxene (wehrlite) and includes abundant homogeneous Al-rich Cr-spinels. These are unique because they appear to record closed-system fractional crystallization rather than magma mixing and because they show that Cr-poor, Al-rich spinel crystallized alongside clinopyroxene. The macrocryst olivine spinel pairs record lower crustal crystal mush conditions with fO2 around the QFM buffer and Tol-liq of 1200C, similar to recharge-related mantles of reverse zoned olivine. More evolved compositions occur in the cores of reverse zoned olivine (Fo75-85) that contain Cr-spinel, Fe-spinel and Almagnetite. Contrary to spinel in more primitive olivine, these compositions are diverse and follow increasing 100Fe3 /(Cr Al Fe3 ) of 12.3 to 54.8 and TiO2 (3.3 to 14.7 wt %) at decreasing Mg# (57.4 to 24.1) and Cr# (30.4 to 9.9) and rapidly increasing oxygen fugacities (Dlog fO2 (QFM) 0.2 to 2.0) over only a limited temperature decrease (Tol-liq: 1190 to 1145C). These compositions span the spinel gap and are extremely rare globally. Their preservation is probably related to hightemperature crystallization followed by rapid cooling. These compositions occur at two of the four investigated volcanic centres (Buoahraun and Berserkjahraun) and indicate a strong influence of crustal magmatic processes on crystal composition and fO2, which is absent in the other two locations (Olafsvikurenni and Nykurhraun). Spinel and olivine compositions support the tectonically controlled decompression melting of a fertile peridotitic source at elevated mantle temperatures relative to MORB and more reducing conditions than other off-rift magmatism in Iceland.
KW - Geothermometry
KW - Magma processing
KW - Mantle source
KW - Olivine
KW - Oxygen fugacity
KW - spinel
U2 - 10.1093/petrology/egab057
DO - 10.1093/petrology/egab057
M3 - Journal article
AN - SCOPUS:85117476268
VL - 62
JO - Journal of Petrology
JF - Journal of Petrology
SN - 0022-3530
IS - 12
M1 - egab057
ER -
ID: 338979245