Crystal chemical formula for sartorite homologues
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Crystal chemical formula for sartorite homologues. / Makovicky, Emil; Topa, Dan.
In: Mineralogical Magazine, Vol. 79, No. 1, 2015, p. 25-31.Research output: Contribution to journal › Journal article › Research › peer-review
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TY - JOUR
T1 - Crystal chemical formula for sartorite homologues
AU - Makovicky, Emil
AU - Topa, Dan
PY - 2015
Y1 - 2015
N2 - The members of the sartorite homologous series are complex sulfides Me 2+ 8N–16–2X Me 3+ 16+X Me + XS8N+8where Me 2+ is Pb and Me 3+ is As and Sb, whereas Me + is Ag and/or Tl. This paper presents calculation formulae for the homologue order N and for the separate substitution percentages for Tl + (As,Sb) ↔ 2Pb and Ag + (As,Sb) ↔ 2Pb substitutions. This enables one to evaluate the crystal chemistry and build a systematic classification of the sartorite homologues
AB - The members of the sartorite homologous series are complex sulfides Me 2+ 8N–16–2X Me 3+ 16+X Me + XS8N+8where Me 2+ is Pb and Me 3+ is As and Sb, whereas Me + is Ag and/or Tl. This paper presents calculation formulae for the homologue order N and for the separate substitution percentages for Tl + (As,Sb) ↔ 2Pb and Ag + (As,Sb) ↔ 2Pb substitutions. This enables one to evaluate the crystal chemistry and build a systematic classification of the sartorite homologues
U2 - 10.1180/minmag.2015.079.1.03
DO - 10.1180/minmag.2015.079.1.03
M3 - Journal article
VL - 79
SP - 25
EP - 31
JO - Mineralogical Magazine
JF - Mineralogical Magazine
SN - 0026-461X
IS - 1
ER -
ID: 147936044